BBC Home Affairs correspondent Daniel Sandford said what was thought to be a letter bomb was found at the Capita building in Victoria Street, Victoria.
London Ambulance said a female employee had been taken to hospital for treatment to her injuries.
Bomb disposal experts were at the scene and Scotland Yard's anti-terrorism command was investigating.
The scene is just 200 yards from Scotland Yard's headquarters. The Capita building remains closed off, but a cordon on Victoria Street has now been lifted.
| | One female employee was injured and taken to a local hospital...her injuries are fairly minor Chief Supt Ian Thomas |
Chief Supt Ian Thomas, of the Metropolitan Police, speaking at the scene, said: "At about 9.40am emergency services were called to the offices behind us following reports of a small explosion.
"We are still investigating the cause of that explosion and the Met Counter Terrorism Command are looking at all the issues involved.
"One female employee was injured and taken to a local hospital and while this is a very traumatic incident for her, her injuries are fairly minor."
A Metropolitan Police spokesman said the counter-terrorism group was leading the inquiry "as a matter of procedure for an incident involving an explosion of this nature".
The Capita Group is a leading business out-sourcing company which runs London's congestion charge system among other services.
All six floors of the office were evacuated.
A spokesman for the company said: "Capita can confirm that a small incident took place at its Victoria street office this morning involving an incendiary device.
"The police have asked us to make no further comment at this time as their investigation is proceeding."
Ben Hetchin, an eye-witness, said: "At first we thought, presumed, it was a fire alert, as we often get, but then a woman was led out with her hands bandaged like a boxing glove, totally covered.
"She looked shocked and shaken, nervous. They then ushered us away behind the police cordon and two firemen said that it was a letter bomb on Victoria Street."
The location of the blast is less than a mile from the Houses of Parliament, Victoria Station and Westminster Abbey.
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